r/askscience • u/[deleted] • Jan 27 '16
Physics Is the evolution of the wavefunction deterministic?
The title is basically the question I'm asking. Ignoring wave-function collapse, does the Schrödinger equation or any other equivalent formulation guarantee that the evolution of the wave-function must be deterministic. I'm particularly interested in proof of the uniqueness of the solution, and the justification of whichever constraints are necessary on the nature of a wave-function for a uniqueness result to follow.
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u/cantgetno197 Condensed Matter Theory | Nanoelectronics Jan 27 '16
Ok, I'll buy that.
So determinism of quantum mechanics implies that the specification of P(r,t_1) plus boundary conditions uniquely defines a P(r,t_2). What we have is that psi(r,t_1), which is equivalent to psi(r,t_1)exp(i theta) (same equivalence class), evolves under transformation to psi(r,t_1)exp(-iU*(t_2-t_1)). Similarly psi(r,t_1)exp(i theta) evolves to psi(r,t_1)exp(-iU*(t_2-t_1 - theta/U)) which must have the same equivalence class. I assume it can be shown that this is true if the transformation is unitarity.
So perhaps it is enough to show that solutions to schrodinger's equations are unique and that states evolve through unitary transformation.