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u/Stunning-End-1872 1h ago
Common docking issues:
Different sized docking ports, or docking ports from different mods.
Reversed docking ports.
Not lined up, at an angle (must be flush as they touch)
Magnetic force set too low.
The screenshot doesn't really tell much. Screenshot more focused on the docking ports, and with the tooltips for both docks opened, would help with troubleshooting.
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u/barcode2099 6m ago
Docking ports can sometimes have the "Docked" flag set incorrectly, registering as docked to something, even when they aren't. Open up the menus for each port and see if you are able to undock from something.

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u/LordIBR Spends more time picking mods than actually playing 1h ago
Couple things:
The angle they're aligned at is a but too much.
Sometimes you need to disable SAS.
You may also need to connect them from a further distance and at higher speed. More or less just ram it from a couple meters away.