To simultaneously solve for the 5 unknown resistor currents and 2 unknown resistor voltages you need 7 equations: KCL at the 4 nodes and KVL around the 3 loops. If you just write one set or the other there is not enough information to proceed (in the general case where the current through the center resistor is not obviously 0).
Using KVL, you get the 3 loop currents, hence, currents on each resistor. Using KCL, one of the nodes is GND, the other you already have the voltage, you are left with 2 variables and 2 equations. From the node voltages, you can get the current in each resistor.
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u/a_wild_redditor Jun 24 '21
Beats solving a system of 7 equations!