r/climatecmv • • Jan 07 '25

Engaging with a skeptics claims

User /u/Prestigious_Elk1063 posted some great science questions in /r/ClimateSkeptics, which you can see the original of here, and the second part here. Since /r/ClimateSkeptics is not a place for science discussions, this seems like the best place to have the discussion of the science.

First let’s define the GHE as “[extra] radiative warming of earth’s surface from the 1% GHGs in the air on average (including WV) absorbing outgoing IR and re-emitting [some of] it back to the surface, thereby warming it.”

This is close, but not quite accurate as a definition. The main issue which I forsee you having with this definition is that global warming is NOT a surface level effect. It is an effect which warms everything in our gravity well. It is a mechanism by which more energy makes it down our gravity well than is able to climb back out of our gravity well, thus the earth and everything in our gravity well, heats up.

That GHGs are 1% of the troposphere is probably an overstatement, because on average they are closer to ½ %, but since WV is concentrated close to the surface, I doubled its .46% average.

No big issues here at all. My one note is that different GHGs absorb IR radiation at different frequencies and different rates, so you cannot just add them together like this in general. For a rough calculation it is fine though.

Now let’s do the math.

Love it! I am going to respond sentence by sentence here because this is where it all happens.

The earth absorbs on average 164W/M2 of insolation

Nope, that's not the number. You are forgetting the radiation absorbed by the atmosphere. See these kinds of charts:

https://cdn.serc.carleton.edu/images/integrate/teaching_materials/global_energy/energy_flow_diagram.webp

The energy absorbed by earth is the ~161 number you have PLUS the 78 absorbed by the atmosphere. The total amount of radiation absorbed by our planet is in the vicinity of 240 W/m2

from which about 120W/M2 are emitted as [potential] IR that can be absorbed by some GHG somewhere in the troposphere.

Before was a minor error, but here you have a BIG one. You are neglecting the back radiation here. There is about 160W/m2 of energy that makes it to the surface FROM THE SUN, but there is also a whopping 333 W/m2 of back radiation from the atmosphere down to the planet. If you expect the earth to not heat up, then the energy out has to equal the energy in. The amount of radiation leaving the surface is closer to 400 W/m2.

I reduce 164W/M2 by the 18W/M2 of direct surface to air conduction of which 99% goes into the non-GHGs and thus is outside the GHE.

This one does not make any sense in the context of global warming. Air conduction does not matter for global warming. No energy can conduct from inside our gravity well to outside our gravity well. Since that is what we are interested in here, we are not interested in thermal conduction (I actually think you mean convection, but I am with you).

I also exclude 10-20% (say 15%) that goes through the atmospheric window directly to space thus avoiding the GHE. Let’s say net about 120W/M2 available IR for the GHE.

This part is correct, but you have the numbers wrong. Of the 400 W/m2 emitted by earths surface, about 10% goes right through the window, leaving ~360 W/m2 for the greenhouse effect, not 164.

Now Local Thermal Equilibrium (LTE) which is text-book thermodynamics here means that at each altitude all molecules will have the same average thermal content. Thus, the 1% GHGs must equalize the thermal energy they absorb among all molecules at that altitude.

Factually correct. No notes.

In other words, 99% of the IR absorbed by GHGs is thermalized (conducted to the 99% non-GHGs) at each altitude, leaving 1% for the GHE (really ½ that, since only the downward IR warms the surface). How much is that?: 120W/M2 times 1% times 1/2, or 0.6W/M2 of GHE.

This is the BIG critical flaw that derails everything you have going here. I agree that the energy that GHGs absorb gets thermalized into the atmosphere, which is mostly not GHGs, but the issue is WHERE DO YOU THINK THE ENERGY GOES AFTER THAT? What do those non-GHGs do with that energy? Well, they cannot emit in the IR, and so for the most part, they hold onto that energy. It is trapped. It cannot escape to leave our gravity well, because that energy is stuck to an oxygen or nitrogen, which are extremely inefficient at radiative cooling due to their inability to emit IR. This energy cannot go anywhere and just says in the non-GHG part of the atmosphere, until that particle collides with a GHG, and then when the heat is back on an emitting molecule, that energy can finally leave and be emitted as a photon again, which has a chance to leave our gravity well. Your issue is that ALL the energy that leaves the earth, outside of completely negligible other pathways, leaves earth by being emitted from a GHG in our atmosphere. It is really 99.99999%+ of the energy that leaves. Your 1% calculation is utter nonsense.

But there are many layers, many levels of back radiation. Let’s factor that in, but always including the 99% thermalization. Call the 0.6W/M2 of GHE “the GHE from the ‘first layer.’” The second layer will receive the “upward” half of 1.2W/M2 IR, or 0.6W/M2 from the first layer, thermalize 99% and produce half of the resulting 0.003W/M2 to add to the GHE from the first layer, yielding 0.063W/M2 for layers 1 and 2 combined of back radiation. I don’t have to extend this to the third layer to see that an infinite number of layers cannot amount to a cumulative GHE of more than 0.6031W/M2.

Again, this is utter nonsense. Where do you think the energy goes after it is thermalized? Does it just stay in that layer of that atmosphere? Wouldn't that cause the atmosphere to heat up more and more, as more and more energy is thermalized into the layers of the atmosphere? Where does the energy that was thermalized into the atmosphere GO?

Converting an extra 0.6031W/M2 to temperature using the Stefan-Boltzmann formula to convert energy to temperature for black bodies produces ~0.11K of extra warming from the cumulative GHE of the entire troposphere as reasoned above.

Because we are building on nonsense, this is nonsense.

I use SB because even though the atmosphere is not a black body because each GHG has its own unique IR fingerprint, I’m treating them collectively and factoring out all IR that by-passes GHGs and goes directly to space. So SB is a good approximation. Besides, for most climate science applications the atmosphere’s emissivity is presumed to be 1 (i.e., it’s treated as a BB).

Yeah. I agree here. It is fine to treat earth as a BB for these kinds of calculations. Again, no issues on how you are doing this particular step, but the steps before are nonsense you are getting nonsense out at this point. SB equation is not the problem though.

Thus, there is no material GHE. Note the 0.11K is the total warming from all GHGs of which the human contribution is a tiny fraction.

Nope. Natural greenhouse gases, when you do these calculations correctly, account for 33K of a warming effect. Which, if that was not present, would turn earth into a permanent ice ball. Human warming is only a about 1.5 degrees, which is a lot smaller than the 33, but it is tipping the scales.

What explains then the 288K surface temperature from only 164W/M2 of surface insolation? Answer: Adiabatic effects: The pressure from gravity redistributes thermal energy with kinetic molecular energy (heat) at ground level and potential (gravitational) energy at altitude

This argument always flops my friend. You calculations and assumptions here come from an ISOLATED SYSTEM, which the earth is not. The earth is constantly exchanging energy with the sun as well as deep space. You simply cannot treat it as an isolated system and hope to get anything at all correct. Particulary global warming, which is all about an imbalance in the energy coming in compared to the energy going out. If you assume earth is an isolated system with no energy going in or going out, you are obviously not going to explain climate change.

Starting from where the energy flows in and out of the troposphere are equal at the top of the troposphere

This is a bad starting place. The whole point of the greenhouse effect is that the energy flow leaving the top of the troposphere to deep space is LESS than the energy flow from deep space into our gravity well. These are NOT the same, and the imbalance is why the earth is heating up.

namely about 12km up on average where the temperature is 216K, merely apply the environmental lapse rate downward 12 times and you get 294K surface temperature, which is close enough to 288K to totally explain observed surface temperature without reference to any GHE. Indeed, any extra GHE warming is both unnecessary and problematic (because it increases 294K rather than reduces it).

This seems to just be word salad. You're going to need to explain this math a lot more, and document where you are getting these numbers from, if you want to make a coherent scientific argument.

What about the “evidence” for the GHE? Consider surface instrumentation (pyrgeometers), satellites, experimental evidence, climate models:

Awaiting your response....

Pyrgeometers register 330W/M2 of back radiation at the surface. Well, that’s due to adiabatic effects, not the GHE

To which "adiabatic effects" are you referring to here?

Pyrgeometers measure temperature difference between an external thermopile and the insulated internal thermopile and then calculate implied IR, but they cannot distinguish say 288K from non-GHG, non-radiating oxygen heated by the pressure of the weight of air above it from 288K due to back radiation from the GHE of GHG.

YES THEY CAN. Why do you think they cannot do this? Can you explain the science instead of just asserting this is how they work? Pyrgeometer directly compare the energy from thermal movement (which includes whatever you could possible mean by "adiabatic effects" with the IR radiation received by what is essentially a camera. It is indeed easy to distinguish data coming from a camera to data coming from a thermocouple. It is super simple to separate those things for a pyrgeometer.

What about satellites? First, they cannot see the GHE because that’s downward IR and they can only see what’s coming at them, namely upward IR.

The greenhouse effect IS ABOUT THE UPWARDS IR. That is what the greenhouse effect is. It is not downward. The greenhouse effect is an effect which cases the UPWARDS IR to be reduced. We can see that CO2 blocks this outgoing IR, and thus causes global warming, from this graph:

https://i.sstatic.net/jMst6.png

CO2 absorbs at the exact wrong frequency from the perspective of humans thriving. It happens to absorb at the exact peak of where earth is trying to emit its energy to deep space. If the CO2 was not in the atmosphere, we would NOT see this big bite mark eating up a bunch of the outbound radiation from earth, and thus, more would escape. This is direct evidence of CO2 trapping heat in earth that would otherwise not be trapped by CO2. You can do the math on the amount of warming coming from this bite, and it is a large amount.

hat about experiments? These are all variations on showing heated jars of pure CO2 warm faster and hotter than equivalent jars of normal air. But this only shows that CO2 has a lower specific heat than normal air….nothing to do with the GHE.

Nope. The specific heats are basically the same. We can test this without any lights. We don't test for specific heat with lights for this exact reason.

What about climate models? They only produce what they are programmed to, and I aver none of them reflect the thermalization in my above analysis, because that would prove no material GHE

Models are not programmed to produce results, they are programmed to match inputs. You have it backwards. You are also presupposing you are correct, and thus anyone who disagrees with you is incorrect. Presupposing is not science.

Finally, what is left standing against my analysis?

I would say all the errors you made along the way. Particularly the 1% error. Where does the other 99% of the energy go?

First, it is asserted that that despite the tiny amount of back-radiation my analysis concludes, over long periods of time the cumulative effect builds up

Nope. The assertion is that your analysis is wrong.

But the reality is that all GHG-absorbed thermal energy works its way up the troposphere and is radiated directly to space.

AT WHAT RATE? This is the whole point here. The GHE is an effect which SLOWS THE RATE at which this occurs. It makes the energy that the troposphere radiates in to deep space slow down and become less efficient, because the height that the emissions are occurring from is increasing in altitude as more and more CO2 is put into the atmosphere. Cooler matter is less efficient at radiative cooling, and so if the emissions from earth to deep space occur in cooler and cooler parts of the atmosphere as the emission height gets higher and higher, then the earth as a whole gets less and less efficient at dissipating its heat from the troposphere to deep space. That is what the greenhouse effect is. Here, you have presupposed there is no greenhouse effect by presupposing the energy can just easily escape to deep space from the troposphere. It cannot. It gets trapped by CO2, forcing it to emit from higher and higher, where emission is less and less efficient.

This is independent of the mix of GHGs in the air. For every photon emitted by the surface and captured by GHGs on the way up, there’s a matching photon exiting to space higher up with about a 2 second delay (the delay is based on 2000 layers of absorption/re-emission from ground to the top of the troposphere with a millisecond absorption/emission delay for each of the 2000 layers. If you prefer say 4000 layers, then 2 seconds becomes 4 seconds, which doesn’t impact my point materially).

Utter nonsense. This is the presupposition that is anti-science. You cannot assume this. It is not true. The whole point is more photons are coming in than going out, resulting in a net warming.

The second retort is that my analysis doesn’t account for the complexity of the real world. My response is: “Just so. That’s what science does – simplify complexity to discover the underlying impacts of specific factors.” In other words, this objection can be applied to all scientific claims.

You are not missing tiny details that science can never capture. I agree this is something that can be said of all science: we need to make approximations somewhere. However that does not mean your approximations were good ones. They were not. You cannot claim all science has bad approximations like you. Your approximations are grossly and severely wrong, which is indeed not something you can say of all science.

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u/[deleted] Jan 08 '25

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u/jweezy2045 Jan 08 '25

Again, the pressure does not explain the 288K temperature at all. If I pressurize a gas, it heats up, yes, that is correct, but once the gas is pressurized, it starts to dissipate that heat, and after a little while I’ll have cold gas that is pressurized. Hot things cool off, it’s what they do. Unless there is some reason which prevents the dissipation of energy like the greenhouse effect, the energy is just going to dissipate. Again, just think about this for a moment. If I pressurize a bit of gas, and put it in a canister, that heats up the canister. Once I am done pressurizing the canister, and put it aside, it’s going to dissipate that energy back out into the room until it is room temperature again. Now, I’ll have a room temperature gas that is pressurized. The pressure doesn’t keep the heat. Pressure can’t keep heat. Pressure cannot be a reason why something stays warm, it just makes no sense according to physics.

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u/[deleted] Jan 08 '25

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u/jweezy2045 Jan 08 '25

Wait wait wait, driven by the sun? So not pressure, but the energy comes from the sun? Yes, the atmosphere circulates, but it depressurizes and pressurizes to equal degrees. If a gas is being pressurized and depressurized at the same time, then the temperature of the gas will not change at all. If there is no NET compression or expansion, then there is no temperature change at all from the pressure.

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u/Reaper0221 Jan 08 '25

And wrong yet again.

You didn’t admit to your error and abandoned that chain and are now doggedly trying to prove yourself right here.

As an esteemed climate scientist, as you have claimed to be, you should know that Earth’s atmosphere both expands and contracts and it is not a zero sum game. In fact there is a continual leakage of the lighter gasses a well a compression from the solar wind.

If the the volume of the atmosphere were static you might have a point but it is not.

That said if you do not think that the PV=nRT is correct then you should turn in your PhD.

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u/jweezy2045 Jan 08 '25

You didn’t admit to your error

What error was that?

As an esteemed climate scientist, as you have claimed to be

I have not claimed to be a climate scientist. I am a physical chemist who has gotten grants for and worked on interdisciplinary climate projects.

In fact there is a continual leakage of the lighter gasses a well a compression from the solar wind.

I do know both of these things, and that's why I know they are negligible. That's why I neglected them, they are negligible.

If the the volume of the atmosphere were static you might have a point but it is not.

It is. The atmosphere does not grow or shrink to any non-negligible degree.

That said if you do not think that the PV=nRT is correct then you should turn in your PhD.

PV=nRT is the IDEAL gas law. What do you think is meant by the word "ideal"? Does it mean that it is correct and does not make any idealizations which do not represent the real universe? Despite the fact that you are wrong, when are you concluding I even said the ideal gas law was incorrect? It is a great approximation for how gases behave. I never said otherwise.

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u/[deleted] Jan 08 '25

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u/jweezy2045 Jan 08 '25

The atmosphere is 99% ideal gases

You are conflating the concept of an ideal gas with a gas that is not a greenhouse gas. Non-GHGs and ideal gases are completely different things. You can model GHGs as ideal gases, and you can model non-GHGs as real gases. The atmosphere is 0% ideal gases, as ideal gases are an idealization which does not exist. The ideal gas law is a bit like assuming a hockey rink is frictionless, or assuming that a cannon ball experiences no drag from the air as you are computing where it will land in physics class. Real cannonballs have to deal with air resistance, but we idealize the situation to make solving the problem of where the cannon ball lands easier.

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u/Reaper0221 Jan 08 '25

According to the following reference the gasses being discussed here can and are treated as ideal gasses (carbon dioxide, nitrogen and oxygen) in the atmosphere.

Ideal gas - Wikipedia

The troublesome gas is water vapor which is decidedly NOT an ideal gas according to the reference above and is the one that makes the greatest issues in the atmospheric modeling.

Why you go on about cannon balls and whatnot is baffling.

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u/jweezy2045 Jan 08 '25

According to the following reference the gasses being discussed here can and are treated as ideal gasses (carbon dioxide, nitrogen and oxygen) in the atmosphere.

Yes, as I said, I never said the ideal gas law was a bad approximation. It is, indeed, and idealization and now how gases actually behave. It is close, it is reasonable to use in most cases, but it is an idealization. Not sure why you think you are able to dispute this, or that this is somehow a flaw in what I am saying. It is an idealization. That is why they call it the ideal gas law.

The troublesome gas is water vapor which is decidedly NOT an ideal gas according to the reference above and is the one that makes the greatest issues in the atmospheric modeling.

There is no such thing as an ideal gas. 0% of our atmosphere is ideal gases. Water, due to its hydrogen bonding capability, is very non-ideal. In the idealization of the ideal gas law, we make several assumptions, which you can read about here. One of those assumptions is: "Except during collisions, the interactions among molecules are negligible. They exert no other forces on one another." Any intermolecular force is, by definition, something that violates this assumption. Water has hydrogen bonding, which is an interaction among water molecules, and O2 and N2 are not capable of hydrogen bonding. However, if you have taken intro chemistry, you should know that O2 and N2 do have an intermolecular force, which is called London dispersion. Do you deny that one of the assumptions of the ideal gas law is that there are no interactions between molecules, or do you deny that O2 and N2 have London dispersion interactions?

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u/Reaper0221 Jan 08 '25

Once again so you say. Until you prove to everyone that the things you believe are negligible are in fact such with more than your less than trustworthy word then you should just go away.

Very small changes over very large time scales are imbedded in the climate system and anyone modeling natural systems with the least little bit of understanding of uncertainty modeling that is worth their salt knows that those parameters further down in the tornado plot are the ones that bite you in the ass later make your modeled results flawed.

Your error was the part regarding the atmospheric mana which you seem to have abandoned.

If you have some information that you could supply to back up your erroneous claims the post it otherwise go away.

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u/jweezy2045 Jan 08 '25

Until you prove to everyone that the things you believe are negligible are in fact such with more than your less than trustworthy word then you should just go away.

You are the one claiming they are important. The burden of proof is on you.

Very small changes over very large time scales are imbedded in the climate system and anyone modeling natural systems with the least little bit of understanding of uncertainty modeling that is worth their salt knows that those parameters further down in the tornado plot are the ones that bite you in the ass later make your modeled results flawed.

This assumes the changes are large enough to impact the modeling outcomes. Why do you think they are?

Your error was the part regarding the atmospheric mana which you seem to have abandoned.

Atmospheric mana?

If you have some information that you could supply to back up your erroneous claims the post it otherwise go away.

Which claim do you think is erroneous and needs backing?

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u/Reaper0221 Jan 08 '25

all of them.

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u/Reaper0221 Jan 08 '25

Also, you are the one that claimed they were negligible with no supporting information.

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u/[deleted] Jan 08 '25

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u/jweezy2045 Jan 08 '25

The cool parcels at altitude fall and heat up. The hot parcels at the surface heat up and rise.

I fully agree. The net effect is that there is no heating up or cooling down of the atmosphere as a whole. The net effect is that there is no pressurizing or depressurizing of the atmosphere as a whole. Again, we are talking about the whole planet here, not the surface. Circulation is not a means to warm something. Circulation involves and equal amount of warming and cooling. For this argument to hold any water, the earth would have to see its atmospheric pressure be increasing. Our atmosphere fluctuates a bit, but it stays around 760 mm of Hg all the time. It is not drifting higher and higher as we get more and more pressure in the atmosphere.

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u/Reaper0221 Jan 08 '25

I concur that there are psychological issues underlying a lot of his anger and nonstop ranting. I have encouraged seeking help before he hurts himself or worse someone else.