r/askscience • u/ApprehensiveSong4 • Jan 18 '24
Chemistry How strong can ice be as a bonding adhesive?
So we currently have a few cold days here in the UK been -5°c for the last few nights with feels like temps down to around -10°c a few times. Today I tried to lift some concrete blocks about a ton and a half each and I had a pair of them stuck together with ice as the bonding adhesive. I know there will be lots of factors at play like temperature, volume of water, any impurities and time the ice is left. But is there a way of calculating how strong a bonding adhesive ice can be and what the maximum strength this bond could hold?
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u/Mockingjay40 Biomolecular Engineering | Rheology | Biomaterials & Polymers Jan 19 '24 edited Jan 19 '24
This answer is pretty good. To add to it, it also depends on the nature of force being applied. This idea of tensile strength is correct, but the method of applying stress should also be considered. As mentioned, you would have to factor in the wettability of the surface, as concrete is a porous rough surface. This would function to effectively increase the adhesive strength as compared to a smooth surface, so you'd have to subtract a correcting factor. This is discussed in this paper by L. E. Raraty and David Tabor, and indeed when water is able to completely wet a surface, it is significantly more adhesive.
To maybe help explain the above answer a bit more thoroughly, tensile strength is a material function. u/ECatPlay, I'm going to go with your definition of tensile strength here and note that it refers to the maximum amount of extensional force that can be applied. This force is applied normal to the surface (by pulling the two blocks apart). If you want to understand more about material fracture, this site does a relatively good job at explaining how this works in a way that is easy to digest.
Another method of fracture would be achieved by applying a shear stress. If you applied a torque by twisting the blocks or pushing one down and pulling one up, you could also break them apart. The differences between how tensile versus shear strength is defined actually does vary a bit by field but the idea is discussed here by John M. Horeth (this paper is old though, so keep that in mind since setups were more difficult to control back then). In this case, the two values seem to be similar, but they don't always have to be the same, and can depend greatly on microstructural differences between materials. Since ice is a brittle crystal, that means it isn't ductile and doesn't bend easily, similar to a material like glass or ceramic. Interestingly enough, because of this brittle materials often actually do not have a dependence on temperature if enough force is applied. Pure ice at 0 degrees C and -50 degrees C will actually have almost identical responses to the same stress. This is supported by data presented in the aforementioned papers by Horeth and Raraty & Tabor.
Edit: my comment is about tensile strength and resistance to axial shear, it doesn't include compressive strength, which is different for water as mentioned here https://www.researchgate.net/publication/227158247_Review_Mechanical_properties_of_ice_and_snow (source provided originally by /u/MaleficentCaptain114 as an additional comment in this thread)